1-D polymer containing the [Ru-N-Ru] μ-nitrido moiety: Crystal structure and magnetic properties of {[Cu(en)2]3[Ru2N(CN)10]· ClO4}n (en = 1,2-diaminoethane)

Xian Ru Sun, Jiang Lin Liang, Chi Ming Che*, Nianyong Zhu, X. X. Zhang, Song Gao

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A novel (μ-nitrido-diruthenium)-bridged 1-D coordination polymer was formed from reaction of K5[Ru2N(CN)10] with [Cu(en)2](ClO)4)2; a similar reaction with [Cu(pn)2][(ClO)4)2] (pn = 1,3-diaminopropane) gave {[Cu(pn)2]5[Ru2N(CN)10] 2} as a discrete molecular compound; variable temperature susceptibility measurements show that there is a weak ferromagnetic interaction between the Cu(II) ions in 1-D polymer.

Original languageEnglish (US)
Pages (from-to)2090-2091
Number of pages2
JournalChemical Communications
Issue number18
StatePublished - 2002
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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